Ni(mpz)_4Cl_2型化合物光磁性质的理论研究  

THEORETICAL RESEARCH ON OPTICAL AND MAGNETIC PROPERTIES OF Ni(mpz)_4 Cl_2 COMPOUND

作　　者：杨复兴[1] 颜占先[1] 周小清[1] 李翠莲[1] 

机构地区：[1]湖南吉首大学物理系,416000

出　　处：《计算物理》1996年第2期232-236,共5页Chinese Journal of Computational Physics

基　　金：湖南省教育委员会科研基金资助课题

摘　　要：利用 d^8(D_(4h)~*)全组态混合统一晶场理论对 Ni(mpz)_4Cl_2型化合物的吸收光谱、基态零场分裂、顺磁 g 因子及顺磁磁化率、磁化强度等进行了统一的计算,理论结果与实验一致,从而对 Ni(mpz)_4Cl_2的光、磁性质作出了完整的、合理的解释。By means of a complete configuration mixing unified crystal field theory for d^8(D_(4h)~*),the optical spectra,the ground state ZFS,EPS parameters,the ground state paramagnetic susceptibility and the magnetization of the Ni(mpz)_4Cl_2 compounds are analysed and calculated systematically.Numerical results agree well with the experimental data,so a complete and reasonable explanation is provicled for the mag- netic of Ni(mpz)_4Cl_2 compounds.

关 键 词：光谱 顺磁磁化率 Ni(mpz)4Cl2型 化合物 吡唑 

分 类 号：O561.2[理学—原子与分子物理] O626.21[理学—物理]