蒸馏妥尔油改性酚醛树脂的合成与应用  

Synthesis and application of modified phenolic resin by distilled tall oil

作　　者：张巧玲[1] 

机构地区：[1]中北大学化学工程系,山西太原030051

出　　处：《应用化工》2005年第9期579-581,共3页Applied Chemical Industry

摘　　要：利用造纸厂纸浆废液中分离出的蒸馏妥尔油,合成了改性酚醛树脂,并对反应机理和树脂结构进行了分析.结果表明,当苯酚与甲醛的摩尔比控制为1:0.6～0.9,蒸馏妥尔油加入量为苯酚的40%～60%时,改性的酚醛树脂性能最佳,与聚合物和溶剂的混溶性得到提高.The modified phenolic resin was synthesized by using distilled tall oil from paper industrial wastes, the reaction mechanism and the structure of resin was analyzed. The results showed that the mole ratio of phenol to formaldehyde is 1 ： 0.6 - 0.9, the content of tall oil is 40% - 60% （mass） of phenol, the properties of modified phenolic resin is good, its compatibility with polymer and solvent was improved.

关 键 词：妥尔油 改性酚醛树脂 酯化 

分 类 号：TQ323.1[化学工程—合成树脂塑料工业]