1,4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构  

Synthesis and Crystal Structure of a Novel Self-assembled (1,4-discyclohexyl cucurbituril) Sodium(I) Complex

作　　者：郑利梅[1] 祝黔江[1] 朱建男[1] 张云黔[1] 陶朱[1] 薛赛凤[1] 魏赞斌[2] 龙腊生[2] 

机构地区：[1]贵州大学应用化学研究所,贵阳550025 [2]厦门大学化学系,厦门361005

出　　处：《无机化学学报》2005年第10期1583-1588,共6页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.20362003);科技部国际科技合作重点项目计划(No.2003DF000030);贵州省省长资金项目;贵州省国际科技合作重点项目计划(No.2005400101)

摘　　要：A novel complex of a new 1,4-dicyclohexyl cucurbituril(DCYQ6) with sodium(I) ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ6 included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ6 with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC: 271400.A novel complex of a new 1,4-dicyclohexyl cucurbituril（DCYQ[6]） with sodium（Ⅰ） ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ[6] included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ [6] with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC： 271400.

关 键 词：1 4-二环己基取代六元瓜环 晶体结构 自组装实体 

分 类 号：O614.112[理学—无机化学]