双异薄荷醇黄原酸镍的吡啶加合物(英文)  

Adduct of Bis(2-isopropyl-5-methylcyclohexyl xanthalato) Nickel(II) with Pyridine

作　　者：叶琼[1] 周挺[1] 瞿志荣[1] 

机构地区：[1]南京大学配位化学研究所,配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2005年第10期1591-1592,共2页Chinese Journal of Inorganic Chemistry

基　　金：973项目(No.G2000077500)

摘　　要：The reaction of homochiral bis(2-isopropyl-5-methylcyclohexyl xanthalato) nickel(II) with pyridine yields an chiral adduct bis(2-isopropyl-5-methylcyclohexyl xanthalato)(dipyridine) nickel(II) (Ⅰ) in which the coordination geometry of the central Ni atom displays a slightly distorted octahedron composed of four S atoms from two xanthalato ligands and two N atoms from pyridine rings. CCDC: 252342.The reaction of homochiral bis（2-isopropyl-5-methylcyclohexyl xanthalato） nickel（Ⅱ） with pyridine yields an chiral adduct his（2-isopropyl-5-methylcyclohexyl xanthalato）（dipyridine） nickel（Ⅱ） （ Ⅰ ） in which the coordination geometry of the central Ni atom displays a slightly distorted octahedron composed of four S atoms from two xanthalato ligands and two N atoms from pyridine rings. CCDC： 252342.

关 键 词：镍 八面体 手性黄原酸 

分 类 号：O614.813[理学—无机化学]