一维链状锰 (Ⅱ)三氮唑配合物的合成,结构与磁性质(英文)  

Synthesis, Structure and Magnetic Property of a One-Dimensional Chain Manganese Compound with 1,2,4-Triazole

作　　者：刘正[1] 周建豪[1] 李一志[1] 宋友[1] 陈学太[1] 

机构地区：[1]南京大学配位化学研究所,配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2005年第10期1601-1604,共4页Chinese Journal of Inorganic Chemistry

基　　金：南京大学分析测试基金资助项目

摘　　要：A novel one-dimensional chain manganese(II) compound Mn(trz)2ClphthH, (trz=1,2,4-triazole, phthH=hydrogen phthalate), 1, was synthesized and structurally characterized. It crystallizes in monoclinic system, space group P2 / c with a=1.381 1(11) nm, b=0.815 5(7) nm, c=0.735 4(6) nm, β=94.667(15)°, V=0.825 5(12) nm3. It consists of one dimensional cationic manganese(II) chain and uncoordinated hydrogen phthalate anions. The manganese(II) ions are bridged with two 1,2,4-traizoles and one chloride anion along the cationic chain, in which the weak antiferromagnetic exchange occurs between manganese(II) atoms. CCDC: 267461.A novel one-dimensional chain manganese（Ⅱ） compound [Mn（trz）2Cl][phthH], （trz=1,2,4-triazole, phthH= hydrogen phthalate）, 1, was synthesized and structurally characterized. It crystallizes in monoclinic system, space group P2/c with a=1.381 1（11） nm, b=0.815 5（7） nm, c=0.735 4（6） nm, β=94.667（15）°, V=0.825 5（12） nm^3. It consists of one dimensional cationic manganese（Ⅱ） chain and uncoordinated hydrogen phthalate anions. The manganese（Ⅱ） ions are bridged with two 1,2,4-traizoles and one chloride anion along the cationic chain, in which the weak antiferromagnetic exchange occurs between manganese（Ⅱ） atoms. CCDC： 267461.

关 键 词：锰配合物 三氮唑 一维链状 磁性质 

分 类 号：O614.711[理学—无机化学]