玻璃基片上纳米碳管电极的集成  

Integration of Carbon Nanotubes Electrodes on Glass Substrate

作　　者：王升高[1] 赵修建[1] 韩建军[1] 汪建华[2] 

机构地区：[1]武汉理工大学硅酸盐材料工程教育部重点实验室,武汉430070 [2]武汉工程大学等离子体化学与新材料重点实验室,武汉430073

出　　处：《物理化学学报》2005年第9期1050-1054,共5页Acta Physico-Chimica Sinica

基　　金：武汉市青年科技晨光计划(20045006071-39);湖北省自然科学基金(2003ABA063);武汉理工大学硅酸盐材料工程教育部重点实验室开发基金(SYSJJ2003-06)资助项目~~

摘　　要：利用微波等离子体化学气相沉积法在玻璃孔穴中定位生长纳米碳管电极,分析了负偏压对纳米碳管电极生长的影响.该电极对铜离子的电化学检测性能分析结果表明,所制备的纳米碳管电极具有良好的电化学检测性能,位于-0.0100V附近的铜离子的还原峰峰形良好,其电流在铜离子浓度为0.01￣0.30mmol·L-1时,与Cu2+浓度呈良好的线性关系,相关系数为0.9975,且具有较好的长期稳定性和重现性.Carbon nanotubes electrodes were prepared in the holes of glass directly by microwave plasma chemical vapor deposition. During the process of carbon nanotubes growth, the negative bias imposed on the substrate could improve the alignment of carbon nanotubes. The electrochemical behavior of CuSO4 at the carbon nanotubes electrode was investigated. Compared to graphite electrode, carbon nanotubes had excellent electrochemical behavior for the analysis of Cu^2＋. The current had linearship with the Cu^2＋ concentration in the range of 0.01～0.30 mmol·L^-1, and the correlation coefficient was 0.9975. Because carbon nanotubes were integrated directly on the substrate, the stable response to Cu^2＋ solution showed that the carbon nanotubes electrodes had long-term stability.

关 键 词：纳米碳管电极 电化学检测 微波等离子体化学气相沉积法 

分 类 号：O646.5[理学—物理化学]