丙烯酸化环状磷腈/环氧丙烯酸酯UV固化体系热降解动力学研究  

Kinetics Study of Thermal Degradation of UV-Cured Acrylated Cyclophosphazene/Epoxy Acrylate Blends

作　　者：姚亮[1] 丁军[1] 瞿保钧[1] 施文芳[1] 

机构地区：[1]中国科学技术大学高分子科学与工程系,合肥230026

出　　处：《化学学报》2005年第19期1834-1840,共7页Acta Chimica Sinica

基　　金：国家自然科学基金(No.50233030);科技部973(No.2001CB409600)资助项目.

摘　　要：以TGA为手段,进行了丙烯酸化环状磷腈/环氧丙烯酸酯光固化体系热降解动力学的研究,同时与加入粉末状环状磷腈混合体系进行了对照.采用Kissinger,Flynn-Wall-Ozawa和Friedman三种方法计算了固化膜降解反应活化能,证明了磷腈结构的引入,使得体系在高温阶段的活化能有所提高,表明降解变得困难,热稳定性得到提高.而反应型丙烯酸化环状磷腈相对粉末状环状磷腈混合体系具有更高的降解活化能.Acrylated cyclophosphazene was used as a flame retardant to blend with commercial UV-curable epoxy acrylate EB600. The kinetics of thermal degradation of the UV-cured product was studied by thermogravimetric analysis at different heating rates in comparison with that to use cyclophosphazene powder in place of the acrylated one. The activation energies and correlation coefficients were calculated by Kissinger, Flynn-Wall-Ozawa and Friedman methods. It has been shown that the addition of cyclophosphazene increased the activation energies of blend systems at high temperature, improved the thermal stability and made the thermal degradation more difficult. Moreover, the acrylated cyclophosphazene film has higher activation energy than that containing cyclophosphazene powder.

关 键 词：环状磷腈 环氧丙烯酸酯 热重分析 降解动力学 热降解动力学 光固化体系 丙烯酸化 动力学研究 磷腈 环状 

分 类 号：O621.25[理学—有机化学]