绿色硝化反应研究进展  

Research Progress of Green Nitration

作　　者：李小青[1] 杜晓华[1] 郑鹛[1] 陈盛[1] 徐振元[1] 

机构地区：[1]浙江工业大学催化加氢研究中心绿色化学合成技术国家重点实验室培育基地,杭州310014

出　　处：《化工进展》2005年第10期1073-1078,共6页Chemical Industry and Engineering Progress

基　　金：浙江省自然科学基金资助项目(Y404033)

摘　　要：介绍了磺酸镧系盐催化硝化、氮氧化物硝化、固体酸催化硝化、液相负载硝化和气相硝化等绿色硝化反应,评述了它们的优缺点,提出了固体氧化物和全氟烷磺酸协同催化NO2/O2绿色硝化反应,有望成为一种有前途的绿色硝化方法。A review, with 47 references, nitration including the application of lan of research progress of some green methods for aromatic thanide（ Ⅲ ） sulfonic salts as catalyst, nitrogen oxides reagents, solid acid as catalyst, solid supported reagents in solution and vapor-phase nitration is presented. Their specific features, merits and demerits are outlined. The potential application of concerted catalyst for green nitration is put forward.

关 键 词：绿色硝化反应 磺酸镧系盐 氮氧化物 固体酸 液相负载 气相硝化 协同催化 

分 类 号：O625.61[理学—有机化学] X383[理学—化学]