Synthesis and Crystal Structure of a Novel Copper (II) Complex with Acetylenedicarboxylate and 2, 2′-Bipyridine  

作　　者：Ming Xing LI Min SHAO Hui DAI Bao Li AN Wen Cong LU Yu ZHU Chen Xia DU 

机构地区：[1]Department of Chemistry, Shanghai University, Shanghai 200444 [2]Department of Chemistry, Zhengzhou University, Zhengzhou 450052

出　　处：《Chinese Chemical Letters》2005年第10期1405-1408,共4页中国化学快报（英文版）

摘　　要：The title compound [Cu （ADC） （2, 2＇-bipy）]n （ADC = C2 （COO）2^2.） was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2＇-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu （Ⅱ） ions, forming coordination polymer structure.The title compound [Cu （ADC） （2, 2＇-bipy）]n （ADC = C2 （COO）2^2.） was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2＇-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu （Ⅱ） ions, forming coordination polymer structure.

关 键 词：Copper complex crystal structure coordination polymer acetylenedicarboxylate acid. 

分 类 号：O614.121[理学—无机化学]