反式-9,10-二氢-9,10-二苄基-9,10-菲二醇的合成与表征  

Synthesis and spectral characterization of trans-9,10-dibenzyl-9,10-dihydro-9,10-phenanthrenediol

作　　者：潘燕琼[1] 洪茵[1] 朱峰[1] 

机构地区：[1]佛山科学技术学院化学与化工系,广东佛山528000

出　　处：《佛山科学技术学院学报（自然科学版）》2005年第3期51-53,共3页Journal of Foshan University(Natural Science Edition)

摘　　要：以菲醌为原料合成了标题化合物,通过IR和1H NM R对其结构进行了表征。氢谱分析表明,亚甲基二氢核构成了AB二级谱自旋体系,这主要是由于孤立亚甲基的2个氢是化学不等价造成的。通过Chem 3D程序模拟得到了标题化合物的能量最优化立体结构。The title compound was synthesized with phenanthrenequinone as starting material and was characterized by IR and 1H NMR spectra. 1H NMR spectra analysis showed that the signals of two hydrogen nuclei of methene formed AB spin system in second-order spectra because of its chemical unequivalence. The mini-energy stereosturcture of the title compound was obtained by Chem3D program.

关 键 词：反式-9 10-二氢-9 10-二苄基-9 10-菲二醇 合成 波谱表征 

分 类 号：O743.5[理学—晶体学]