异羟肟酸过渡金属配合物仿加氧酶研究进展  

Recent advance in transition-metal complexes of hydroxamic acid as oxygenase models

作　　者：徐斌[1] 刘富安[1] 冯发美[1] 李建章[1] 

机构地区：[1]四川理工学院化学系,自贡643000

出　　处：《西南民族大学学报（自然科学版）》2005年第6期906-910,共5页Journal of Southwest Minzu University(Natural Science Edition)

基　　金：四川理工学院校级科研项目(2004ZR009)

摘　　要：综述了异羟肟酸过渡金属配合物仿加氧酶研究进展新进展,重点综述了异羟肟酸过渡金属配合物的结构对其二氧加合性能、催化苯乙烯环氧化性能以及催化乙苯、二甲苯和异丙苯均相氧化性能的影响。In this article, the recent advance is reviewed in transition-metal complexes of hydroxamic acid as oxygenase models. Also reviewed are the influences of the structure of transition-metal complexes of hydroxamic acid on their dioxygen affinities, catalytic epoxidation of styrene and catalytic oxidation activity in xylene, cumene and phenylethane homogenous oxidation.

关 键 词：异羟肟酸 过渡金属配合物 仿加氧酶 研究进展 

分 类 号：O641.4[理学—物理化学]