间异丙基甲苯催化氧化的研究  

Study on the Catalytic Oxidation of m Cymene

作　　者：张铭俊[1] 张秀峰[1] 王桂霞[1] 奚祖威[1] 

机构地区：[1]中国科学院大连化学物理研究所

出　　处：《石油化工》1996年第6期381-385,共5页Petrochemical Technology

摘　　要：探索了间异丙基甲苯氧化生成氢化过氧化物的氧化催化剂，旨在提高生成氢化过氧化物的速度和选择性。考察了某些无机盐、有机盐、金属络合物、有机碱、有机膦和含氮有机物对氧化的影响，找到了一种复合催化剂，可以缩短氧化反应的时间，并提高生成氢化过氧化物的选择性。Various catalysts for the oxidation of m cymene to form hydroperoxides were researched in order to shorten oxidation reaction time and enhance selectivity The effect of inorganic and organic salts,metal complexes,organic bases,organic phosphates and organic nitrogenous compounds on the oxidation time and selectivity was investigated A complex catalyst which can reduce oxidation time and raise selectivity was found and evaluated

关 键 词：间异丙基甲苯 催化氧化 催化剂 甲酚 

分 类 号：O625.311[理学—有机化学] O643.3[理学—化学]