铜酞菁磺酸苯酯的光谱性质研究  

Synthesis and Spectral Properties of Copper Phthalocyanine Sulfonic Phenyl Ester

作　　者：殷焕顺[1] 邓建成[1] 向能军[2] 

机构地区：[1]湘潭大学化学学院,湘潭411105 [2]中山大学化学与化学工程学院,广州510275

出　　处：《染料与染色》2005年第5期19-20,共2页Dyestuffs and Coloration

摘　　要：将铜酞菁氯磺化,与苯酚酯化,合成了标题化合物。在不同的溶剂中测试其电子光谱:Q带吸收峰为:664.6nm～672.4nm,强度为0.363～1.477;B带吸收峰336.8nm～348.4nm,强度为:0.181～0.708。产物的荧光光谱随溶剂的极性减弱而强度降低:DMF>THF>CH_2Cl_2>DMSO>丙酮>吡啶>CHCl_3;其波长随溶剂的极性减弱而发生蓝移:DMSO>THF>DMF>丙酮>CH_2Cl_2>吡啶>CHCl_3。Copper phthalocyanine sulfonic phenyl ester was synthesized from copper phthalocyanine by chlorosultbnating, then estentymg with phenol. The product was characterized by means of IR, UV-Vis, element analysis and TG. It was found that the derivative has good dissolution in some organic solvents. Besides, the properities of electrochemistry and spectra were determined.

关 键 词：铜酞菁 电子光谱 荧光光谱 

分 类 号：TQ610.1[化学工程—精细化工]