C_（60）硝基化合物的合成与性质  

SYNTHESIS OF C_(60) NITRO-DERIVATIVES AND STUDY OF THE PROPERTIES

作　　者：黄克雄 孙红英[1] 李晶[1] 李新海[1] 黄欢[1] 孙铭良[1] 

机构地区：[1]中南工业大学冶金物理化学与化学新材料研究所

出　　处：《中南工业大学学报》1996年第1期109-112,共4页Journal of Central South University of Technology(Natural Science)

基　　金：中国有色金属工业总公司高新技术科研基金;巴陵石油化工公司科研基金

摘　　要：在惰性介质ＣＣｌ４溶剂中，将Ｃ６０分别与浓ＨＮＯ３及ＮＯ２反应制备Ｃ６０硝基化合物，并通过红外光谱、紫外光谱、元素分析等方法确定了Ｃ６０硝基化合物的结构为Ｃ６０（ＮＯ２）ｘ（ＯＨ）ｙ·其中，Ｃ６０与ＨＮＯ３反应合成时，ｘ为２～３，ｙ为１２～１４；与ＮＯ２反应合成时，ｘ为３～５，ｙ为１２～１６·C60 nitro-derivatives were prepared by reacting C60 in the inert CCl4 solution with concentrated HNO3 and NO2 gas respectively. The products were studied by means of IR, UV and elemental analysis etc. And the formulas were ascertained to be C60(NO2)x(OH)y where x=2~3,y= 12~ 14 or x= 3~5,y= 12~ 16 in the product obtained by concentrated HNO3 or NO2 gas respectively.

关 键 词：硝基化合物 合成 性质 碳 

分 类 号：O613.71[理学—无机化学] O621.3[理学—化学]