大环草酰胺配合物CuC_(33)H_(28)Cl_2N_4O_3的合成和晶体结构(英文)  

Synthesis and Crystal Structure of Macrocyclic Oxamide Complex CuC_(33)H_(28)Cl_2N_4O_3

作　　者：周旭光[1] 孙亚秋[2] 王庆伦[3] 杨光明[3] 廖代正[3] 

机构地区：[1]天津工业大学材化学院,天津300160 [2]天津师范大学化学学院,天津300074 [3]南开大学化学学院,天津300071

出　　处：《无机化学学报》2005年第12期1853-1856,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.59973008);天津市自然科学基金(No.013603711)资助项目

摘　　要：A novel macrocyclic oxamide complex CuL (L=C33H28Cl2N4O3) has been synthesized and characterized by elemental analysis, IR spectrum, UV-Visible spectrum and single crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n. The lattice parameters are: a=0.848 8(3) nm, b=1.904 9(7) nm, c=1.868 1(7) nm, β=92.794 (6)° and V=3.016 8(19) nm3, Z=4. The results show that the coordination geometry around copper(II) in the complex is aberrant tetragonal-plane. CCDC: 265601.A novel macrocyclic oxamide complex CuL （L=C33H28Cl2N4O3） has been synthesized and characterized by elemental analysis, IR spectrum, UV-Visible spectrum and single crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n. The lattice parameters are： α=0.848 8（3） nm, b=1.9049（7） nm, c=1.868 1（7） nm, β=92.794 （6）° and V=3.016 8（19） nm^3, Z=4. The results show that the coordination geometry around copper（Ⅱ） in the complex is aberrant tetragonal-plane. CCDC： 265601.

关 键 词：大环草酰胺配合物 晶体结构 光谱表征 

分 类 号：O614.121[理学—无机化学]