四-α-(2,2,4-三甲基-3-戊氧基)酞菁金属配合物(M=Co,Ni,Cu,Zn)的合成与光谱性质(英文)  

Synthesis and Spectroscopic Property of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) Phthalocyaninato] Metal Complexes (M=Co, Ni, Cu, Zn)

作　　者：江舟[1] 陈耐生[1] 王俊东[1] 黄金陵[1] 

机构地区：[1]福州大学化学化工学院功能材料研究所,福州350002

出　　处：《无机化学学报》2005年第12期1891-1896,共6页Chinese Journal of Inorganic Chemistry

基　　金：福建省自然科学基金资助项目(No.E0310007)。

摘　　要：A series of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) phthalocyaninato] metal complexes(M=Co, Ni, Cu, Zn)were prepared by cyclotetramerization of 3-(2,2,4-tirmethyl-3-pentoxy)phthalonitrile with corresponding anhydrous metal salts, using 1.8-diazabicyclo[5.4.0] undec-7-ene (DBU) as the catalyst. HPLC analysis shows that one isomer predominates in the product of nickel complex, while at least two main constitutional isomers exist in the product of other metal complexes. The complexes (in the form of mixture of constitutional isomers) were characterized by elemental analyses, MS, IR and UV-Vis spectroscopy.A series of [tetra-α-（2,2,4-tirmethyl-3-pentoxy） phthalocyaninato] metal complexes（M=Co, Ni, Cu, Zn） were prepared by cyclotetramerization of 3-（2,2,4-tirmethyl-3-pentoxy）phthalonitrile with corresponding anhydrous metal salts, using 1.8-diazabicyclo[5.4.0] undec-7-ene （DBU） as the catalyst. HPLC analysis shows that one isomer predominates in the product of nickel complex, while at least two main constitutional isomers exist in the product of other metal complexes. The complexes （in the form of mixture of constitutional isomers） were charac- terized by elemental analyses, MS, IR and UV-Vis spectroscopy.

关 键 词：酞菁金属配合物 光谱性质 构造异构体 

分 类 号：O614.33[理学—无机化学]