Synthesis and Crystal Structure of Bismuth（Ⅲ） Complexes Bi（1,10-phen）[S2CN（CH3）2]2（NO3）, {Bi（S2COCH3）[S2CNC6Hs（CH3）]2}2 and [Bi（S2CNBu2）2（CH3OH）（NO3）]∞  

作　　者：尹汉东 王传华 邢秋菊 

机构地区：[1]Department of Chemistry, Liaocheng University, Liaocheng, Shandong 252059, China

出　　处：《Chinese Journal of Chemistry》2005年第12期1631-1636,共6页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （No. 20271025）, the Natural Science Foundation of Shandong Province （No. L2003B01）.

摘　　要：Three bismuth（Ⅲ） complexes Bi（1,10-phen）[S2CN（CH3）2]2（NO3） （1）, {Bi（S2COCH3）[S2CNC6Hs（CH3）]2}2 （2） and [Bi（S2CNBu2）2（CH3OH）（NO3）]∞ （3） were synthesized and characterized by elemental analysis and IR spectra. Their crystal structures were determined by X-ray single crystal diffraction analysis. Studies show that complex 1 has a monomeric structure with the central bismuth atom eight-coordinated in a capped distorted pentagonal bipyramidal geometry. The complex 2 takes centrosymmetric dimeric structure and the bismuth atoms are seven-coordinated in distorted pentagonal bipyramidal geometry.In complex 3, the bismuth atoms are seven-coordinated in distorted pentagonal bipyramidal geometry by bridging nitrate O atoms and the resulting structure is onedimensional infinite chain polymer.Three bismuth（Ⅲ） complexes Bi（1,10-phen）[S2CN（CH3）2]2（NO3） （1）, {Bi（S2COCH3）[S2CNC6Hs（CH3）]2}2 （2） and [Bi（S2CNBu2）2（CH3OH）（NO3）]∞ （3） were synthesized and characterized by elemental analysis and IR spectra. Their crystal structures were determined by X-ray single crystal diffraction analysis. Studies show that complex 1 has a monomeric structure with the central bismuth atom eight-coordinated in a capped distorted pentagonal bipyramidal geometry. The complex 2 takes centrosymmetric dimeric structure and the bismuth atoms are seven-coordinated in distorted pentagonal bipyramidal geometry.In complex 3, the bismuth atoms are seven-coordinated in distorted pentagonal bipyramidal geometry by bridging nitrate O atoms and the resulting structure is onedimensional infinite chain polymer.

关 键 词：bismuth（Ⅲ） complex DITHIOCARBAMATE XANTHATE crystal structure 

分 类 号：O614.532[理学—无机化学]