改性蜂窝陶瓷催化臭氧化降解水中微量硝基苯  

Degradation of Nitrobenzene in Aqueous Solution by Modified Ceramic Honeycomb-Catalyzed Ozonation

作　　者：孙志忠[1] 赵雷[1] 马军[1] 

机构地区：[1]哈尔滨工业大学市政环境工程学院,哈尔滨150090

出　　处：《环境科学》2005年第6期84-88,共5页Environmental Science

基　　金：国家自然科学基金项目(50378028)

摘　　要：以硝基苯为目标反应物,对改性蜂窝陶瓷、蜂窝陶瓷催化臭氧化和单独臭氧氧化去除水中微量有机污染物的效果进行了比较.发现与单独臭氧氧化相比,改性蜂窝陶瓷和蜂窝陶瓷催化臭氧化工艺可以提高水中硝基苯的去除率,分别为38.35%和15.46%.在本次实验条件下,随着改性蜂窝陶瓷催化剂的用量增加到5份,硝基苯的降解效率上升了30.55%;3种工艺对硝基苯的去除率都随着温度的升高而显著增加,随着pH值的升高越来越大,在pH=10.00左右时,臭氧/改性蜂窝陶瓷联用对硝基苯的去除优势消失;臭氧/改性蜂窝陶瓷催化氧化对硝基苯的去除遵循自由基机理;催化剂对硝基苯的吸附很小,对去除几乎没有影响;对于3个体系,将总量相同的O3多次投加可以获得明显优于一次性投加的去除效果;改性蜂窝陶瓷催化剂的使用寿命较长.Comparative experiments of modified ceramic honeycomb, ceramic honeycomb-catalyzed ozonation and ozonation alone were conducted with nitrobenzene as the model organic pollutant. It was found that the processes of modified ceramic honeycomb and ceramic honeycomb-catalyzed ozonation could increase the removal efficiency of nitrobenzene by 38.35% and 15.46% , respectively, compared with that achieved by ozonation alone. Under the conditions of this experiment, the degradation rate of modified ceramic honeycomb-catalyzed ozonation increased by 30.55 % with the increase of amount of catalyst to 5 blocks. The degradation rate of three process all increased greatly with the increase of temperature and value of pH in the solution. But when raising the pH value of the solution to 10.00, the advantage of modified ceramic honeycomb-catalyzed ozonation processes lost. The experimental results indicate that in modified ceramic honeycomb-catalyzed ozonation, nitrobenzene is primarily oxidized by · OH free radical in aqueous solution. The adsorption of nitrobenzene is too limited to have any influence on the degradation efficiency of nitrobenzene. With the same total dosage of applied ozone , the multiple steps addition of ozone showed a much higher removal efficiency than that obtained by one step in three processes. Modified ceramic honeycomb had a relative longer lifetime.

关 键 词：催化臭氧化 改性蜂窝陶瓷 硝基苯 降解 

分 类 号：TU991.2[建筑科学—市政工程] X520.5[环境科学与工程—环境工程]