一种新颖的层状[(H_3O)_2V_3O_8]_n钒簇化合物的水热合成  

The Hydrothermal Synthesis of a Novel Layer [(H_3O)_2V_3O_8]_n Vanadium Cluster Compound

作　　者：洪军[1] 

机构地区：[1]吉林师范大学化学学院,吉林四平136000

出　　处：《吉林师范大学学报（自然科学版）》2005年第4期15-16,共2页Journal of Jilin Normal University:Natural Science Edition

摘　　要：[(H3O)2V3O8]n为钒氧原子交替健和形成的二维层状结构．这种[5,4]拓扑结构层在[001]平面上堆 积,层与层之间填充着做为抗衡阳离子的水合氢离子．The compound in the title is a two - dimensional layer structure. The structure is formed by the alternated linkage of vanadium oxonium atom. The [5,4] topological framework layer stacks in the [001] plane and fills the aquated hydrogen ion among the layers. These ions are the counter positive ions.

关 键 词：钒簇化合物 水热合成 晶体结构 

分 类 号：O611.4[理学—无机化学]