沙枣糖合成烷基糖苷工艺的研究  

Study of synthesis processing of alkyl polyglycosides from oleaster sugar

作　　者：吕兴连[1] 王青宁[1] 康文术[1] 

机构地区：[1]兰州理工大学石油化工学院,甘肃兰州730050

出　　处：《兰州理工大学学报》2005年第6期70-73,共4页Journal of Lanzhou University of Technology

摘　　要：以沙枣糖和脂肪醇为原料,采用正交试验L16(45)进行烷基糖苷的合成,找出了合成烷基糖苷较佳的工艺条件:反应温度115～120 ℃,常压反应,反应时间5～7 h,m沙枣糖:m乙二醇:m正十二醇=1:2:1.2,选用0.8%的对甲苯磺酸和0.2%的十二烷基苯磺酸的混合酸为催化剂.沙枣糖转化率达87.5%,产物表面张力为29.1～33.7 mN/m.通过红外光谱对产物的结构进行了分析.Taking the oleaster sugar, ethandiol, ano 1-dodecanol as raw material, the alkyl polyglycosides was synthesized by means of orthogonal experiment L16 （4^5）, and a better processing condition of synthesis of alkyl polyglycosides found：reaction temperature is 115-120 ℃,reaction time of 5-7 h,mass ratio of oleaster sugar to ethandiol and dodecanol of 1 ： 2 ： 1.2,and the catalyst is mixed acid from 0. 8% p-toluenesulfonic acid and 0.2% dodecyl benzenesulfonic acid. The conversion rate of oleaster amounts to 87. 5% and surface tension is 29. 1-33. 7 mN/m,The structure of resultant was analyzed with spectrography.

关 键 词：沙枣糖 烷基多糖苷 正交试验 合成 

分 类 号：TQ423.2[化学工程]