芳维A酸糖酯的合成与结构表征  

Synthesis and Characterization of Glycosyl Esters Derivatives of all-trans-Aritinoic acid

作　　者：党奎峰[1] 陈超越[1] 殷小秋[2] 尹凯[1] 向建南[1] 

机构地区：[1]湖南大学化学化工学院,湖南长沙410082 [2]湖南大学医院,湖南长沙410082

出　　处：《精细化工中间体》2005年第6期32-34,43,共4页Fine Chemical Intermediates

基　　金：教育部留学归国人员基金(No.2003406);国家自然科学基金(No.20472018);湖南省自然科学基金(No.03JJY3016)

摘　　要：在碳酸钠和四丁基溴化铵催化下,将芳维A酸分别与O-乙酰基溴代葡萄糖、O-乙酰基溴代木糖、O-乙酰基溴代乳糖、O-乙酰基溴代麦芽糖作用,制得相应的芳维A酸乙酰基糖酯。并以IR、MS1、HNMR确认了4个糖酯的结构。Four new glucosyl esters of all-trans-aritinoic acid were synthesized by the reaction of all-trans- aritinoic acid with O-acetylglucopyranosyl bromide or O-acetylgalactopyranosyl bromide, O-acetylgalactopyranosyl bromide, O-acetylgalactopyranosyl bromide in the presence of sodium carbonate and Bu4NBr. Their structures were confirmed by IR、^1H NMR and MS.

关 键 词：芳维A酸 糖酯 合成 表征 

分 类 号：O62[理学—有机化学]