玻璃纤维化学镀Ni-Co-Fe-P合金工艺的研究  

A Study of Electroless Ni-Co-Fe-P Plating on Glass Fibers

作　　者：时刻[1] 黄英[1] 廖梓 朱峰[1] 祖恩峰[1] 

机构地区：[1]西北工业大学应用化学系,陕西西安710072 [2]解放军后勤工程学院军事油料应用与管理工程系,重庆400016

出　　处：《电镀与环保》2005年第6期16-19,共4页Electroplating & Pollution Control

基　　金：航天支撑技术基金资助项目(2002EK1803)

摘　　要：在玻璃纤维表面化学镀Ni-Co-Fe-P合金,用扫描电镜、能谱仪和X射线衍射仪对其进行了表征。研究了Ni-Co-Fe-P化学镀液中Fe2+/(Ni2++Co2++Fe2+)摩尔比和镀液pH值对化学沉积镀速、镀层成分以及镀层电阻率等影响。镀层在镀态时为非晶结构,镀层Ni61.3Co19.2Fe9.1P10.4的晶化过程为:非晶态→Ni→Ni+Ni5P2→Ni+Ni3P+FeNi3。The deposits of Ni-Co-Fe-P alloys on the glass fibers were successfully prepared by electroless plating process, and are characterized by scanning electron microscope, energy dispersive spectroscopy, X-ray diffraction analysis. The effects of the mole ratio of Fe^2＋/（Ni^3＋＋Co2＋＋Fe^2＋ ）nd pH in the bath on the deposition rate composition and resistivity of the eleetroless Ni-Co-Fo-P deposits are investigated. The as-plated Ni-Co-Fe-P alloy deposits are of amorphous structure. The crystallization processes of the Ni61.3Co19.2Fe9.1P10.4 deposits is as follows： amorphous→Ni→Ni＋Ni5P2→Ni＋Ni3P＋FeNi3.

关 键 词：化学镀 玻璃纤维 Ni-Co-Fe-P 工艺 结构 

分 类 号：TQ153.1[化学工程—电化学工业]