水/有机两相体系长链烯烃氢甲酰化反应中TPPTS和TPPMS的协同效应  

Synergistic effect of TPPTS and TPPMS on 1-decene hydroformylation catalyzed by water-soluble phosphine-rhodium complex

作　　者：李诚[1] 袁茂林[1] 付海燕[1] 陈华[1] 李贤均[1] 

机构地区：[1]四川大学化学学院有机金属铬合催化研究所绿色化学与技术教育部重点实验室,四川成都610064

出　　处：《化学研究与应用》2006年第1期9-12,共4页Chemical Research and Application

基　　金：国家重大基础研究计划(973)资助项目(2000048008)

摘　　要：在RhC l(CO)(TPPTS)2-TPPTS-CTAB作为催化剂的水-有机两相催化体系中,详细考察了TPPTS与TPPMS的摩尔比、催化剂浓度、表面活性剂的浓度、搅拌速度等反应条件对1-癸烯氢甲酰化反应活性和区域选择性的影响。研究结果表明:在保持体系中总的膦/铑摩尔比不变的情况下,加入TPPMS对催化活性影响不大,但可明显提高区域选择性。当[TPPTS]/[TPPMS]=1时,表现出较好的协同催化效应,生成醛的正/异比从没加TPPMS时的5.9增加到了11.5。同时,催化剂浓度、表面活性剂的结构和浓度、搅拌速度等反应的活性和区域选择性都有重要影响。In this paper the influences of various parameters, such as the molar ratio of TPPTS to TPPMS, concentration of RhCl （CO） （TPPTS）2, concentration of CTAB, on the catalytic activity and regioselectivity of 1 - decene hydroformylation were investigated in aqueous/organic two - phase catalytic system containing cationic surfactants. The addition of TPPMS as a modifier increased the regioselectivity for the linear aldehyde. A synergistic effect of TPPTS and TPPMS increasing the regioselectivity was observed. The molar ratio of linear to branched aldehyde increased from 5.9 （ without TPPMS） to 11.5 （ [TPPTS ] / [ TPPMS ] = 1 ： 1 ）.

关 键 词：氢甲酰化反应 1-癸烯 水-有机两相催化 表面活性剂 协同效应 

分 类 号：O623.12[理学—有机化学] O623.121[理学—化学]