车用燃料油吸附法深度脱硫技术进展  

Progress in Deep Desulfurization for Vehicle Fuel Oil by Adsorption

作　　者：王云芳[1] 尹风利[2] 史德清[1] 杨金荣[1] 孔瑛[1] 

机构地区：[1]中国石油大学(华东)重质油国家重点实验室,山东东营257061 [2]中国石化集团胜利石油有限公司胜利采油厂工艺研究所,山东东营257051

出　　处：《石油化工》2006年第1期94-99,共6页Petrochemical Technology

基　　金：中国石油天然气集团公司石油科技中青年创新基金项目(03E7025)

摘　　要：综述了车用燃料油吸附法深度脱硫的技术及吸附机理,主要包括物理吸附脱硫、化学吸附脱硫、络合吸附脱硫和选择性吸附脱硫等。物理吸附是极性吸附,吸附剂对硫化物的选择性差,难以对燃料油进行深度脱硫;化学吸附能对燃料油进行深度脱硫,但吸附温度和吸附剂再生温度较高;络合吸附和选择性吸附脱硫技术操作条件温和、投资和操作费用低,能深度脱硫,可生产硫含量小于50μg/g的低硫车用燃料油,但目前吸附剂对含硫芳烃的选择性和容硫量还较低,不能满足工业应用的要求。Deep desulfurization for vehicle fuel oil by adsorption was reviewed. The desulfurization mechanism included physical adsorptive desulfurization, chemical adsorptive desulfurization, complex adsorptive desulfurization and selective adsorptive desulfurization. The effect of physical adsorption depended on polarity of sulfur and was not expected to be very selective for sulfocompounds in vehicle fuel oil and subsequent deep removal of sulfur. The chemical adsorbents were superior for sulfur removal from the low sulfur content oil, but it demanded high adsorption temperature and high adsorbent regeneration temperature. The techniques of complex adsorption desulfurization and selective adsorption desulfurization were predominant because of their low investment,low operation charge and high desulfurization efficiency. Vehicle fuel oil with sulfur content less than 50 μg/g could be obtained by utilizing the techniques. But sulfur holding capacity of adsorbents and their selectivity for sulfurous aromatics could not yet satisfy the requirement in industrial application.

关 键 词：车用燃料油 脱硫 物理吸附 化学吸附 络合吸附 选择性吸附 

分 类 号：TQ028.15[化学工程]