羰基合成高碳醇工艺研究进展  

Advances in process for hydroformylation of higher olefins to higher alcohol

作　　者：谭波[1] 蒋景阳[1] 金子林[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室,辽宁大连116012

出　　处：《现代化工》2006年第1期10-14,16,共6页Modern Chemical Industry

基　　金：教育部博士点科研基金资助项目(20020141004);国家自然科学基金资助项目(20376013)

摘　　要：综述了对液/液两相催化高碳烯烃氢甲酰化制备高碳醇的研究进展,针对经典的水/有机两相体系不能用于催化高碳烯烃氢甲酰化的问题,全面介绍了适用于水/有机两相体系中高碳烯烃氢甲酰化的温控相转移催化法等6种改进方法。同时对氟两相、离子液体两相、超临界流体等非水液/液两相体系中的高碳烯烃氢甲酰化作了系统阐述,并对它们的应用前景进行了评价。The advances in hydroformylation of higher olefins to higher alcohol in liquid/liquid biphase systems were reviewed.Aiming at the problems that the classical aqueous/organic biphase system is unsuitable for the hydroformylafion of higher olefins, six kinds of improved methods including the thermoregulated phase-transfer catalysis were introduced in detail. In addition,the hydroformylation of higher olefins in nonaqueous liquid/liquid biphase systems, such as the fluorous biphasic system, non-aqueous ionic liquid biphasic system and supercfitical fluid biphasic system, were also introduced. Meanwhile, the possibilities of commercial applications of each system were discussed.

关 键 词：高碳烯烃 氢甲酰化 高碳醇 水/有机两相 温控相转移催化 

分 类 号：TQ223.127[化学工程—有机化工]