在Cu^（2＋）PCS及乙醇－水体系中α－萘酚的氧化  

Oxidation of α-naphthol catalyzed by bi-nucleus copper sulfo-phthalocyanine in ethanol-water

作　　者：孙强[1] 邓桂胜[1] 姚小华 苏永成 张振权 

机构地区：[1]东北师范大学化学系

出　　处：《化学试剂》1996年第3期138-140,共3页Chemical Reagents

基　　金：吉林省自然科学基金

摘　　要：研究了在乙醇－水体系中ＣａＣｌ２为助催化剂时不同因素对Ｃｕ２＋ＰＣＳ催化氧化α－萘醌制α－萘醌的影响，并确定了最佳催化反应条件。Various effects such as catalyst weight, reaction temperature, α-naphthol weight, CaCl2 weight, volume ratio of ethanol to water and reaction time on the oxidation of α-naphthol to α-naphthoquinone by oxygen with bi-nucleus copper sulfo-phthalocyanine as catalyst and CaCl2 as co-catalyst were studied. The best catalytic conditions for this reaction were obtained.

关 键 词：Α-萘酚 α-萘醌 催化氧化 双核磺化酞菁铜 

分 类 号：O625.313[理学—有机化学] O627.12[理学—化学]