萜烯－马来酸酐不饱和聚酯树脂的合成及其性能研究  

SYNTHESIS OF TERPENE-MALEIC ANHYDRIDE UNSATURATED POLYESTER RESINS AND THEIR PROPERTIES

作　　者：钱昱辉 安鑫南[1] 

机构地区：[1]中国林业科学研究院林产化学工业研究所,南京林业大学

出　　处：《林产化学与工业》1996年第2期33-37,共5页Chemistry and Industry of Forest Products

摘　　要：以优级松节油为原料，合成萜烯－马来酸酐加成物（简称ＴＭ）．再以ＴＭ、马来酸酐、二元醇等为基料，合成了几种不饱和聚酯树脂（ＴＭ－ＵＰ树脂）．讨论了不同配方及合成工艺与树脂产品性能的关系，并对其物化性能、树脂浇铸体力学性能及耐腐蚀性能等进行了测试，从中选出了几种综合性能较好、工艺较简单、成本较低的ＴＭＡ－ＵＰ树脂配方．通过比较得知制得的ＴＭ－ＵＰ树脂性能达到或超过通用型商品ＵＰ树脂，完全可代替通用型商品ＵＰ树脂应用．Terpene-maleic anhydride adduct(TM) is obtained from Diels-Alder reaction between terpene and maleic anhydride. Instead of phthalic anhydride which is usually used in ordinary unsaturated polyester resin (UP-resin) ,TM is used in synthesizing several TMUP-resins. Results of quality tests confirm that some of TM-UP-resin compositions have good overall characteristics and obtained by a simple technological process. Compared with the ordinary commercial UP-resin ,TM-UP-resin has the similar qualities , but better heat stability and lower cost. Hence , it can be used instead of ordinary UP-resin.

关 键 词：萜烯 马来酸酐 不饱和聚酯树脂 聚酯树酯 合成 

分 类 号：TQ323.42[化学工程—合成树脂塑料工业]