顺序氯化对微生物、副产物和生物稳定性的综合控制  

Simultaneous Control of Microorganism,Disinfection By-Products and Bio-Stability by Sequential Chlorination Disinfection

作　　者：陈超[1] 张晓健[1] 何文杰[2] 韩宏大[2] 朱玲侠[1] 王云[1] 刘静[1] 

机构地区：[1]清华大学环境科学与工程系,北京100084 [2]天津市自来水集团有限公司,天津300040

出　　处：《环境科学》2006年第1期74-79,共6页Environmental Science

基　　金：国家高技术研究发展计划(863)项目(2002AA601140);国家自然科学基金重点项目(50238020)

摘　　要：在中试规模试验中，研究了“短时游离氯后转氯胺的顺序氯化消毒工艺”对微生物、消毒副产物和生物稳定性指标的控制效果．该顺序氯化消毒工艺综合利用了游离氯消毒灭活微生物迅速彻底，氯胺消毒副产物生产量低的特点，通过氯化消毒技术的组合，安全经济地实现了消毒卫生学和消毒副产物指标的双重控制．该消毒工艺对细菌总数、异养菌平板计数、总大肠菌群指标的控制效果略好于传统游离氯消毒，对脊髓灰质炎病毒和大肠杆菌f2噬菌体的灭活效果与游离氯相同．相同原水条件下，顺序氯化消毒工艺比游离氯消毒工艺产生的三卤甲烷浓度减少35．8％～77．0％；卤乙酸减少36．6％～54．8％．消毒进水水质越差，顺序氯化消毒工艺在消毒副产物控制方面就越有优势．该工艺对生物稳定性指标的控制效果明显高于游离氯消毒．A new safe chlorination disinfection process, the sequential disinfection process with short term free chlorine plus ehloramines was investigated its efficiency on control of indices of microorganism, disinfection by-products and bio-stability. This disinfection process may take the advantage of free chlorine＇ s quick inactivation of microorganism and chloramines＇ low DBP yield and long term residual. Thus, both control of microorganisms and DBPs can be achieved effectively and economically. The pilot test results show that safe chlorination disinfection process has a little better efficiency on total bacteria count, HPC and total coliform count than free chlorination disinfection, which indicate that free chlorine and chloramines might have the synergetic disinfection effect for their different attacking targets. It also had the same inactivation efficiency on polio virus and coliphage f2 as free chlorination in 120 minutes contact time. Sequential chlorination disinfection process could reduce 35.8% -77.0% yield of trihalomethane and 36.6% -54.8% yield of haloacetic acids. The poorer quality the water had, the more advantage the safechlorination disinfection had than free chlorination disinfection one. Moreover, sequential chlorination had better efficiency on biostability control than free chlorination.

关 键 词：消毒 游离氯 氯胺 顺序氯化 消毒副产物 细菌 病毒 

分 类 号：TU991.25[建筑科学—市政工程] X52[环境科学与工程—环境工程]