Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups  

作　　者：Gang LIU Feng HE Yah Ping WANG Jun FENG Ren Xi ZHUO 

机构地区：[1]Key Laboratory of Biomedical Polymers of Ministry of Education, Department of Chemistry, Wuhan University, Wuhan 430072

出　　处：《Chinese Chemical Letters》2006年第1期137-139,共3页中国化学快报（英文版）

基　　金：support of the National Natural Science Foundation of China(Grant No.20104005)

摘　　要：A new six-membered cyclic carbonate monomer, 5-allyloxytrimethylene carbonate （ATMC）, was synthesized starting from glycerol, and the corresponding polycarbonates, poly（5-allyloxytrimethylene carbonate）（PATMC） were further synthesized by ring-opening polymerization in bulk at 150℃ using stannous octanoate as an initiator. The structures of the monomer and the polymers were confirmed by IR, IH-NMR, 13C-NMR, and GPC analysis.A new six-membered cyclic carbonate monomer, 5-allyloxytrimethylene carbonate （ATMC）, was synthesized starting from glycerol, and the corresponding polycarbonates, poly（5-allyloxytrimethylene carbonate）（PATMC） were further synthesized by ring-opening polymerization in bulk at 150℃ using stannous octanoate as an initiator. The structures of the monomer and the polymers were confirmed by IR, IH-NMR, 13C-NMR, and GPC analysis.

关 键 词：5-Allyloxytrmethylene carbonate poly（5-allyloxytrimethylene carbonate） ring-opening polymerization POLYCARBONATE allyl ether. 

分 类 号：O633.1[理学—高分子化学]