顺-1-环己基-1,2-环己二醇的合成  

SYNTHESIS AND SPECTRAL ANALYSIS OF cis-1-CYCLOHEXYL-1,2-CYCLOHEXANEDIOL

作　　者：张颂培[1] 祝钧[1] 陈娟[1] 

机构地区：[1]北京工商大学化工学院,北京100037

出　　处：《精细石油化工》2006年第1期20-22,共3页Speciality Petrochemicals

摘　　要：研究了顺-1-环己基-1，2-环己二醇的合成新工艺。先用格氏试剂1-环己基溴化镁和环己酮反应制得环己醇，醇脱水后生成α-位取代的环己烯，最后用甲酸-过氧化氢氧化制得顺-1-环己基-1，2-环己二醇。产物用元素分析、红外光谱与^1H NMR进行了表征。产物熔点90～91℃，收率为29％。1-cyclohexyl-cyclohexanol was prepared by the reaction of grignard reagent and cyclohexanone and the product was then dehydrated to give 1-cyclohexyl-1,2-cyclohexene. cis-1-cyclohexyl-1, 2-cyclohexandiol was obtained by the oxidization of 1-cyclohexyl cyclohexene with hydrogen peroxide. The melting point（90 -91℃） of the product was the same as the reported value. The elemental analysis, IR and ^1H NMR data all indicated that the target compound was prepared.

关 键 词：顺1-1环己基-1 2-环己二醇 合成 表征 

分 类 号：TQ233[化学工程—有机化工]