季戊四醇螺环磷酸苯酚酯的合成及结构表征  

Synthesis and Characterization of Bis-phenol Ester of Spirocylic Pentaerythritol Bis-chlorophosphatidic Acid

作　　者：孙才英[1] 李斌[1] 张转芳[1] 邵博[1] 徐树财[1] 

机构地区：[1]东北林业大学化学化工系,哈尔滨150040

出　　处：《应用化学》2006年第2期165-168,共4页Chinese Journal of Applied Chemistry

基　　金：黑龙江省自然科学基金(9805);东北林业大学校基金资助

摘　　要：以水作溶剂,季戊四醇螺环磷酰二氯与苯酚在碱性条件下反应,得到季戊四醇螺环磷酸苯酚酯。用反应体系中的苯酚钠在269.6 nm处的吸光度变化跟踪反应进程,确定反应时间。用IR1、H NMR以及磷元素分析测试技术表征了产品结构。用TG法分析了产品的热稳定性。With water as solvent, the bis-phenol ester of spirocylic pentaerythritol bis-chlorophosphatidic acid was prepared from spirocyclie pentaerythritol bis-chlorophosphatide and phenol under alkaline condition. The reaction time was determined by monitering the reaction process with the absorbency variation of phenol sodium in the reaction system at 269. 6 nm. The product structure was characterized with FTIR, ^1H NMR and the phosphorus amount. The thermal stability of the product was analysed with TG measurement.

关 键 词：季戊四醇螺环磷酸苯酚酯 季戊四醇螺环磷酰二氯 苯酚 绿色合成 

分 类 号：O627[理学—有机化学]