主族元素取代的11-钨铜杂多配合物的合成、表征及性质研究  

Synthesis,characterization and properties of 11-heteropolytungstocopper compounds containing main-group elements

作　　者：王丽丽[1] 周百斌[1] 张旭[1] 马慧媛[1] 徐学勤[1] 韦永德[2] 

机构地区：[1]哈尔滨师范大学化学系,黑龙江哈尔滨150080 [2]哈尔滨工业大学应用化学系,黑龙江哈尔滨150001

出　　处：《分子科学学报》2006年第1期18-23,共6页Journal of Molecular Science

基　　金：国家自然科学基金资助项目(20371014);黑龙江省自然科学基金资助项目(ZTB2005-33);黑龙江省高校骨干教师创新计划资助项目(1055G016);黑龙江省教育厅科研项目(10531070);哈尔滨市学科后备带头人基金资助项目(2002AFXXJ050)

摘　　要：合成了ⅡA,ⅣA,ⅤA族元素为取代原子的3个系列钨铜杂多配合物.经ICP,TG曲线确定其化学式为K8[CuZ(OH2)W11O39].xH2O和K17,18[Z′(CuW11O39)2].xH2O(Z=Mg,Ca;Z′=Sr,Ba,Sn,Pb,Sb,Bi).通过TG-DTA,IR,XRD,XPS,183W-NMR等手段对合成配合物结构进行了表征,并对其进行了讨论.结果表明,新配合物具有典型的Keggin结构,且主族元素进入到配合物的骨架中.由于新配合物中CuⅡ具有顺磁性,导致XPS,183W-NMR的测试结果表现出特殊性;用循环伏安法测定了新配合物的电化学性质,表明均为可逆氧化还原过程,还对导电性和热稳定性进行了研究.Three series of heteropolytungstocopper compounds containing ⅡA, ⅣA and ⅤA element have been prepared. The molecular formulas are confirmed as K8 [CuZ（OH2） W11O39 ]·xH2O and K17.18[Z＇ （CUW11O39）2]xH2O（Z= Mg, Ca; Z＇= Sr, Ba, Sn, Pb, Sb, Bi） by ICP and TG. Their structures are characterized by TG-DTA, IR,XRD, XPS,183 W-NMR measurements. The results show that the new compounds are of Keggiu structure, and the main group elements have already entered into the skeletons of new compounds. Because the Cuu in the compounds is paramagnetic, the special properties are shown in the results of XPS,^183W-NMR, and discussed in the paper. Furthermore, according to Cyclic Voltammetry, their electrochemical properties are determined, the result indicts that all the redox processes are reversible, the conductivity and the thermalstabilities of the compounds are also studied,

关 键 词：主族元素 杂多配合物 电化学性质 导电性 

分 类 号：O614[理学—无机化学]