铜(Ⅱ)—二肽配合物的配位形式、结构和稳定性研究进展  

Developments of the coordination mode,structure and stabilization of copper(Ⅱ)-dipeptide complexes

作　　者：古琴[1] 乐学义[1] 

机构地区：[1]华南农业大学应用化学系,广东广州510642

出　　处：《化学研究与应用》2006年第2期113-121,共9页Chemical Research and Application

基　　金：广东省自然科学基金重点项目(04105986);华南农业大学新学科扶持基金(2003X004)资助项目

摘　　要：本文概述了近几十年来铜(Ⅱ)—二肽配合物的研究进展,介绍了铜(Ⅱ)—二肽体系几种常见的配位方式,以及溶液和晶体中的二肽铜配合物的结构。对配合物的稳定性进行了讨论,着重介绍了二肽的光学异构对配合物稳定性的影响。The studie, of copper（ Ⅱ ） -dipeptide complexes in the last decades have been summarized in this paper. Several familiar coordination modes of copper（ Ⅱ ） - dipeptide systems as well as the structures of the dipeptide complexes with copper in solution and crystal have been reviewed. Moreover,the stabilization of the complexes,especially the influence of the optical activity of dipeptide on the stabilization has been discussed.

关 键 词：铜(Ⅱ)—二肽体系 配位形式 结构 稳定性 

分 类 号：O641.4[理学—物理化学]