3,5,3’,5’-四叔丁基-苄烯-4,4’-醌的合成和分子结构  

Synthesis and crystal structure of 3,5,3',5'-tetra-tert-butyl-stilbene-4,4'-quinone

作　　者：袁福根[1] 丁春羊[1] 居萍萍[1] 

机构地区：[1]苏州科技学院化学化工系,江苏苏州215009

出　　处：《化学研究与应用》2006年第2期202-203,共2页Chemical Research and Application

基　　金：江苏省青蓝工程(HB2001-27)项目资助;江苏省教育厅基金(04KJD560171)项目资助

摘　　要：Reaction of sodium 2,6-di-tert-buty1-4-methylphenolate with CuCl o CuCl2 in THF affords metallic copper and 3,5,3’,5’-tetra-tert-butyl-stilbene4,4’-quinone in good yield.The product was characterized by melting point,elemental analysis,IR,MS and X-ray cerystallography.The molecular structure of the title compound was for the first time elucidated.Reaction of sodium 2,6 - di - tert - butyl - 4 - methylphenolate with CuC1 o CuC12 in THF affords metallic copper and 3,5,3＇ ,5＇ - tetra - tert - butyl - stilbene - 4,4＇ - quinone in good yield. The product was characterized by melting point, elemental analysis ,IR, MS and X- ray eerystallography. The molecular structure of the title compound was for the first time elucidated.

关 键 词：酚 氧化偶联 分子结构 

分 类 号：O626.43[理学—有机化学]