N,N,N′,N′-四炔丙基-4,4′-二氨基-二苯甲烷与4,4′-联苯二苄叠氮固化动力学研究  

Cure Kinetics Study of the Polymerization of N,N,N′N′-Tetrapropargyl-p,p′-Diamino Diphenyl Methane with 1,1′-Bezidomethyl-4,4′-biphenyl

作　　者：罗永红[1] 扈艳红[1] 万里强[1] 薛莲[1] 周围[1] 黄发荣[1] 沈学宁[1] 齐会民[1] 杜磊[2] 陈祥宝[3] 

机构地区：[1]华东理工大学材料科学与工程学院超细材料制备与应用教育部重点实验室,上海200237 [2]中国航天科技集团公司第八研究院,上海200233 [3]北京航空材料研究院,北京100095

出　　处：《高等学校化学学报》2006年第1期170-173,共4页Chemical Journal of Chinese Universities

基　　金：国家重大基础研究'九七三'计划(批准号:5131101);国家高技术研究发展计划'八六三'计划(批准号:2002AA305103);武器装备预研基金(批准号:51412020103QT3111)资助

摘　　要：分别利用FTIR和DSC技术对由N,N,N,′N′-四炔丙基-4,4′-二氨基-二苯甲烷(TPDDM)与4,4′-联苯二苄叠氮(BAMBP)形成的一种新型三唑树脂的固化反应及其动力学进行了研究.TPDDM与BAMBP通过1,3-偶极环加成反应形成三唑五元环结构的聚合物,固化起始温度约为70℃,体系在较低温度下即可固化.反应体系的固化反应是一级反应,采用DSC法与FTIR法分别获得了表观聚合反应动力学参数,其结果具有一定的可比性.A novel low temperature curing resin was prepared by the 1,3-dipolar cycloaddition polymerization of N, N, N＇, N＇-tetrapropargyl-p ,p＇-diamino diphenyl methane （ TPDDM ） and 1,1 ＇-bezidomethyl-4,4＇-biphenyl （BAMBP） at 70 ℃. The variation of TPDDM with BAMBP of the reactively functional groups during the polymerization was traced by FFIR, the polymerizing reaction of TPDDM with BAMBP and the reaction kinetics were investigated using FFIR and differential scanning calorimetry（DSC） at a variety of heating rates. The kinetic parameters at different temperatures including the reaction order, activation energy and pre-exponential factor were obtained. The apparent reaction order n, activation energy Ea and pre-exponential factor A calculated from F＇FIR and DSC data were mutually evidential.

关 键 词：TPDDM BAMBP 1 2 3-三唑聚合物 固化反应动力学 

分 类 号：O631[理学—高分子化学]