纳米CaCO_3复合微粒对ABS性能的影响  

STUDY ON THE EFFECT OF NANO-CaCO_3 COMPOSITE PARTICLE TO ABS

作　　者：张雪琴[1] 毋伟[1] 曾晓飞[1] 俞江华[1] 陈建峰[1] 

机构地区：[1]纳米材料先进制备技术与应用科学教育部重点实验室教育部超重力工程研究中心北京化工大学,北京100029

出　　处：《高分子材料科学与工程》2006年第1期107-110,共4页Polymer Materials Science & Engineering

基　　金：国家自然科学基金重点项目(20236020);国家杰出青年基金项目(20325621)

摘　　要：将苯乙烯(S t)、丙烯酸丁酯(BA)双单体在纳米碳酸钙粒子存在下的水相悬浮液中进行无皂乳液聚合,制备出纳米碳酸钙聚合物复合微粒,研究了复合微粒对改性纳米C aCO3/ABS复合材料力学性能的影响及增韧机理。结果表明,复合微粒以纳米级均匀分散在基体中,与基体间形成良好的柔性界面层;复合材料的断面产生了大量的滑移和褶皱,起到了吸收和分散机械力的作用。当单体的配比和种类适当时,复合微粒对ABS有很好的改性作用,其填充量为3份(质量)时,复合材料单缺口冲击强度达到40.6kJ/m2,比纯ABS提高24.5%,拉伸强度基本不变。Nano-calcium carbonate/polymer composite particle was prepared by polymerization of styrene （St） and butyl acrylate （BA） on the surface of nano-CaCO3 in aqueous suspension. The effects of composite particle to the structure and the mechanical properties of nano-CaCO3/ABS composite material and the toughening mechanisms were studied. The results show nano- CaCO3 particles disperse well in matrix at nano-scale and it exists flexible interface between them. ‘Drape and slippage ＇ structure exists in the composite materials, which takes effect on adsorption and dispersion mechanical energy. When the ratio and sort of monomer are rational, soapless emulsion polymerization with double monomers is a good way of nano-CaCO3 modification. The single-notched impact strength of composite materials reaches 40.6 kJ/m^2 and is improved 24. 5% compared to pure ABS as the mass ratio of nano-CaCOs composite particle and ABS was 3 ： 100.

关 键 词：纳米碳酸钙 丙烯腈-丁二烯-苯乙烯共聚物 复合材料 增韧 

分 类 号：TB383[一般工业技术—材料科学与工程]