铁(Ⅲ)卟啉丙烯酸酯-苯乙烯共聚物的合成及其催化环己烷羟化作用  

Synthesis of A New Iron(Ⅲ) Porphrin Acylate-styrene Copolymer and Its Catalysis for Hydroxylation of Cyclohexane

作　　者：余汉城[1] 陈鲜丽[1] 李锡贤[1] 黄锦汪[1] 计亮年[1] 

机构地区：[1]中山大学化学与化学工程学院,广东广州510275

出　　处：《中山大学学报（自然科学版）》2006年第1期61-63,共3页Acta Scientiarum Naturalium Universitatis Sunyatseni

基　　金：国家自然科学基金资助项目(20071034);广东省自然科学基金资助项目(021726)

摘　　要：合成了铁(Ⅲ)卟啉丙烯酸酯-苯乙烯共聚物并以UV-V IS,IR,ICP和相对分子质量测定进行了表征。研究了共聚物模拟细胞色素P450催化环己烷羟化作用,发现该共聚物具有比未以高分子负载的铁(Ⅲ)卟啉高很多的催化活性,循环使用多次后其催化活性基本不变,以铁(Ⅲ)卟啉周围微环境的观点讨论了实验结果。A new iron（ Ⅲ ） porphrin acylate-styrene copolymer, P[ （PorFe）A-S ], was synthesized by the reaction of iron （Ⅲ） porphrin acylate with styrene and characterized by UV-Vis, IR, ICP and molecular weight determination. Its catalytic activity in hydroxylation of cyclohexane for model cytochrome P450 in the P[ （PorFe）A- S]-O2-ascrobate-thiosalicylic acid system has been studied. It was found that the P[ （PorFe）A-S] has a higher catalytic activity than non-supported iron （Ⅲ） porphyrin and its high catalytic activity remained in reuse. The catalytic activity of P[ （PorFe）A-S ] was discussed in the view of the microenvironment of iron（ Ⅲ ） porphyrin. It is proposed that the catalytic activity of the P[ （PorFe）A-S] may be further enhanced by construction of a homophase catalytic system containing the iron（ Ⅲ ） porphyrin acylate-styrene copolymer.

关 键 词：铁(Ⅲ)卟啉丙烯酸酯-苯乙烯共聚物 合成 催化 环己烷羟化作用 

分 类 号：O643[理学—物理化学]