Al-SBA-15介孔分子筛的合成、表征及其在苯酚叔丁基化反应中的催化性能  

Synthesis, Characterization, and Catalytic Performance of Mesoporous Al-SBA-15 for Tert-butylation of Phenol

作　　者：吴淑杰[1] 黄家辉[1] 吴通好[1] 宋科[1] 王虹苏[1] 邢丽红[1] 徐海燕[1] 徐玲[1] 管景奇[1] 阚秋斌[1] 

机构地区：[1]吉林大学化学学院,吉林长春130023

出　　处：《催化学报》2006年第1期9-14,共6页

基　　金：国家重点基础研究发展计划(973计划)(2004CB217804);吉林省科技发展计划(20020806)资助项目.

摘　　要：通过嫁接的方法合成了AlSBA15介孔分子筛,用X射线衍射、透射电子显微镜、低温N2吸附和NH3程序升温脱附等方法进行了表征,并研究了其在苯酚叔丁基化反应中的催化性能.结果表明,AlSBA15保持了母体SBA15高度有序的六方介孔结构,具有较强的酸性,且在苯酚叔丁基化反应中表现出比AlMCM41更好的催化活性和2,4二叔丁基苯酚选择性.Mesoporous Al-SP, A-15 was successfully synthesized by post-synthesis grafting Al atoms on parent siliceous SBA-15. Both SBA-15 and Al-SBA-15 with different Si/Al ratios were characterized by powder X-ray diffraction, transmission electron microscopy, and N2 adsorption-desorption methods. The analytic results show that the hexagonal p6mm mesostructure of parent siliceous SBA-15 is maintained very well in Al-SBA-15. NH3 temperature-programmed desorption result indicates that Al-SBA-15 has both medium and strong acid sites. During the alkylation of phenol with tert-butanol, the Al-SBA-15 catalyst displays higher conversion of phenol and selectivity for 2,4-di-tert butyl phenol （2,4-DTBP） than traditional Al-MCM-41 catalyst, At the reaction temperature of 145℃ , a high phenol conversion of 75.2% and 2,4-DTBP selectivity of 31.3% over Al-SBA-15 are observed, but those over Al-MCM-41 are only 61.3 % and 13.4 %, respectively. Due to the large pore size （about 9 nm） which is beneficial to the effective diffusion of reactants and products, obvious catalyst deactivation of Al-SBA-15 is not observed even after reaction for 5 h.

关 键 词：Al—SBA-15分子筛 苯酚 叔丁醇 烷基化 4-叔丁基苯酚 2 4-二叔丁基苯酚 

分 类 号：O643.36[理学—物理化学]