2,3-二氯-1,4-萘醌的合成工艺研究  

Study on Synthesis of 2,3-Dichloro-1,4-naphthaquinone

作　　者：曹晓群[1] 刘欣[1] 程岳山[1] 

机构地区：[1]泰山医学院化学与化学工程学院,山东泰安271000

出　　处：《精细与专用化学品》2006年第3期16-17,共2页Fine and Specialty Chemicals

摘　　要：研究了以1,4-萘醌为原料,三氯化铁为催化剂,甲苯作溶剂的催化氯化制备2,3-二氯-1,4-萘醌的合成工艺。研究确定的最佳工艺条件为:反应温度100℃;催化剂用量0·6%(以占1,4-萘醌质量计);溶剂甲苯用量为每克1,4-萘醌15mL。产品收率达到88·4%,纯度为98·9%。2,3-Dichlero-1,4-naphthaquinone is synthesized by catalytic chlorination of 1,4-naphthaquinone in presence of iron trichloride. The optimum reaction conditions are as follows： the reaction temperature is 100℃ , the catalyst dosage is 0. 6 % by weight of the 1,4-naphthaquinone and the dosage of methylbenzene taken as solvent is 15 mL per lg 1, 4-naphthaquinone. The yield of product is 88.4% and the purity is 98.9%.

关 键 词：2 3-二氯-1 4-萘醌 1 4-萘醌 催化氯化 

分 类 号：TQ242[化学工程—有机化工]