Ni(PZ)_4Cl_2型化合物的光谱及EPR参量  

THE SPECTRUM AND EPR PARAMETERS OF THE COMPOUND Ni(PZ)_4Cl_2

作　　者：颜占先[1] 杨复兴[1] 周小清[1] 蒋光和[1] 鲁邦德[1] 戴薇[1] 

机构地区：[1]吉首大学物理系,湖南吉首416000

出　　处：《吉首大学学报》1996年第1期43-46,共4页

摘　　要：本文利用d8（D1h）全组态混合统一晶场理论对Ni（PZ）4Cl2型化合物的吸收光谱、基态ZFS、EPR参量进行了统一的计算和理论分析，理论结果与实验一致。从而对其光、磁性质作出完整、合理、统一的解择。By means of a complete configuration mixing unified crystal field theory for d8(D4h),the optical spectra, the ground state ZFS、EPR parameters of Ni (PZ)4Cl2 compounds are analysed and calculated theoretically and systematically in this paper. All results agree well with the experimental data,so as to obtain a complete and teasonable explanation for the optical and magnetic properties of Ni (PZ)4Cl2 compounds.

关 键 词：Ni(PZ)4Cl2 光谱 EPR参量 镍离子 

分 类 号：O614.813[理学—无机化学]