新型疏水性固体酸ZR(SO_4)_2/AC催化剂的制备及其催化性能  被引量:26

Preparation and Catalytic Performance of Novel Water-Tolerant Zr(SO_4)_2/AC Solid Acid Catalyst

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作  者:张敬畅[1] 孟秀娟[1] 曹维良[1] 

机构地区:[1]北京化工大学现代催化研究所可控化学反应科学与技术基础教育部重点实验室,北京100029

出  处:《催化学报》2006年第2期135-138,共4页

基  金:国家自然科学基金(20076004);中石化资助项目

摘  要:将Zr(SO4)2(CZ)负载在活性炭(AC)上制备疏水性固体酸CZ/AC催化剂,用于丙烯酸与正辛醇的酯化反应,考察了催化剂制备条件对催化剂活性和疏水性的影响.结果表明,以60~80目的活性炭负载30%的Zr(SO4),并于110℃干燥后制得的CZ/AC催化剂的活性最高,丙烯酸转化率可达100.0%;CZ/AC催化剂循环使用3次,丙烯酸的转化率仍保持在97.5%.采用X射线衍射(XRD)、傅里叶变换红外光谱(FT、IR)、X射线光电子能谱(XPS)和低温N,吸附方法对催化剂的结构和酸性进行了表征,XRD及XPS测试结果均表明硫酸锆以非晶态形式高度分散在活性炭的表面;原位红外吸附NH,测试中在1521和1695cm^-1处有两个吸收峰,表明催化剂表面存在L酸和B酸.负载型疏水性固体酸CZ/AC催化剂的酸强度、酸量、催化活性和疏水性能均高于Zr(SO4)2.The water-tolerant CZ/AC (CZ-Zr(SO4)2) solid acid catalyst was prepared by supporting zirconium sulfate on activated carbon (AC) and used for esterification of acrylic acid and n-octanol. The effect of preparation conditions on the catalytic activity and hydrophobicity of CZ/AC was investigated. The CZ/AC catalyst was characterized by X-ray diffraction (XRD) and in situ Fourier transform infrared spectroscopy (FT-IR). Assessment experiments show that when 30% CZ is supported on AC of 60-80 mesh and dried at 110℃ , CZ/AC shows the highest activity, and the conversion of acrylic acid is 100.0%. After reused for 3 times, the conversion of acrylic acid is still 97.5 %. XRD results indicate that zirconium sulfate is finely dispersed on AC, and no crystalline is observed. The bands at 1521 and 1 695 cm^-1 assigned to acid sites are observed by in situ FT-IR for CZ/AC after adsorbing ammonia, indicating that CZ/AC has both Lewis acid sites and Bronsted acid sites. The acidity, catalytic activity, and hydrophobicity of the supported CZ/AC Catalyst are higher than those of unsupported Zr(SO4)2.

关 键 词:疏水性固体酸 硫酸锆 活性炭 负载型催化剂 丙烯酸 正辛醇 酯化 

分 类 号:O643.36[理学—物理化学]

 

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