超微盘电极上苯胺的循环扫描伏安法电化学聚合  

Electrochemical Polymerization of Aniline by Cyclic Voltammetric Method at Ultramicrodisk Electrode

作　　者：杨周生[1] 张祖训[1] 

机构地区：[1]南京大学化学系,南京210093

出　　处：《分析化学》1996年第5期559-562,共4页Chinese Journal of Analytical Chemistry

摘　　要：本文对超微盘电极上苯胺的循环扫描伏安法电化学聚合进行了研究。对聚合过程的伏安曲线性质以及峰电流和单体浓度、循环扫描次数和速率及电位之间的关系作了详细的探讨，还给出了峰电流的经验式。The electrochemical polymerization of aniline by cyclic voltammetric method at ultramicroelectrode is investigated. The properties of voltammetric curve during the polymerization and the relationships among the peak current (ip)a, the concentration of monomer(Cr), the number of cycles (N), the sweeping rate and the potentiaI (E.) are discussed in detail. The empirical equation for peak current during the polymerization is obtained.

关 键 词：伏安法 电化学聚合 超微盘电极 苯胺 

分 类 号：O633.21[理学—高分子化学] O631.5[理学—化学]