基于最小自由能法的烟火药燃烧产物预测模型  

Calculational Model of Pyrotechnical Combustion Products Based on Minimum Free Energy

作　　者：宋东明[1] 潘功配[1] 王乃岩[1] 

机构地区：[1]南京理工大学化工学院,南京210094

出　　处：《弹箭与制导学报》2006年第1期120-122,共3页Journal of Projectiles,Rockets,Missiles and Guidance

基　　金：国防预研基金项目(41305070201)

摘　　要：燃烧产物的预测对烟火药的设计非常重要。文中采用最小自由能法原理,建立了烟火药燃烧产物预测模型,使用傅立叶变换红外光谱仪对实际燃烧产物进行了分析。在预测产物与实际燃烧产物对比的基础上,修正了理化参数数据库后,预测结果同实际产物完全相同,验证了模型的合理性。A model of pyrotechnical combustion products was established based on the principle of minimum free- energy. Actual products was analyzed by FTIR and compared with calculational result. After thermodynamic and physical property data was corrected, two results were identical. This confirmed the rationality of model.

关 键 词：最小自由能 烟火药 燃烧产物 预测模型 

分 类 号：TQ567.5[化学工程—炸药化工]