基于氢键作用结合的超分子聚合物  

Supramolecular Polymers Formed Through Hydrogen-Bonded Noncovalent Interactions

作　　者：王毓江[1] 唐黎明[1] 

机构地区：[1]清华大学化学工程系高分子研究所,北京100084

出　　处：《化学进展》2006年第2期308-316,共9页Progress in Chemistry

摘　　要：非共价键结合的超分子聚合物由于其特殊的结构及性能引起了广泛的关注。本文在介绍超分子化学、氢键及超分子聚合物的基础上,主要综述了以氢键为结合力的多重氢键作用、羧基(D)与吡啶基(A)作用以及氢键与其它非共价键协同作用形成的超分子聚合物体系,并对超分子聚合物的研究现状及前景进行了评述。Supramolecular polymers formed through noncovalent interactions have attracted great attention recently due to their special structures and properties. The supramolecular chemistry, hydrogen bond and supramolecular polymers are introduced. Supramolecular polymers formed by different hydrogen-bonded systems, including multiple-hydrogen- bonded interactions, hydrogen bond formed from carboxylic acids and pyridines, and multiple interactions including hydrogen bond and other noncovalent bond, are reviewed in detail. The research status quo and the perspective of supramolecular polymers are discussed.

关 键 词：超分子聚合物 氢键 合成 超分子化学 

分 类 号：O631[理学—高分子化学] O641.3[理学—化学]