Synthesis, Characterization and Biological Activity of Transition Metals with Schiff Base Derived from Adamantaneamineand o-Vanillin  

作　　者：ZHAO Guoliang LI Liangchao LIU Xinghai ZHANG Pinghua 

机构地区：[1]College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, China

出　　处：《Wuhan University Journal of Natural Sciences》2006年第2期427-431,共5页武汉大学学报（自然科学英文版）

基　　金：SupportedbyZhejiangEducationDepartmentFoundation(20030711)

摘　　要：Five new solid complexes were synthesized about transition metals with Schiff base（ L, C18H23NO2 ） derived from adamantaneamine and o-vanillin, and characterized by elemental analysis, molar conductance, infrared spectra, UV-vis spectra, thermal analysis. Their chemical formula are [ML2]（ClO4）2 （ M= Mn, Co, Ni, Cu, Zn）, and the coordination numbers are four, The antibacterial activity of Schiff base ligand and its complexes was studied.Five new solid complexes were synthesized about transition metals with Schiff base（ L, C18H23NO2 ） derived from adamantaneamine and o-vanillin, and characterized by elemental analysis, molar conductance, infrared spectra, UV-vis spectra, thermal analysis. Their chemical formula are [ML2]（ClO4）2 （ M= Mn, Co, Ni, Cu, Zn）, and the coordination numbers are four, The antibacterial activity of Schiff base ligand and its complexes was studied.

关 键 词：transition metal complex Schiff base adamantaneamine crvanillin biological activity 

分 类 号：O623.621[理学—有机化学]