超声波照射合成双二苯基膦烷烃的研究  

Study on synthesis of di(diphenylphosphine)-alkanes by ultrasonic wave

作　　者：马淮凌[1] 曹广秀[1] 李贯良[1] 杜美菊[1] 

机构地区：[1]商丘师范学院化学系,河南商丘476000

出　　处：《应用化工》2006年第3期176-179,共4页Applied Chemical Industry

基　　金：河南省自然科学基金项目(0511020300);商丘市科技攻关项目(20055001)

摘　　要：以锂片、三苯基膦、二氯代烷烃为主要原料，合成了Ph2P（CH2）nPPh2（n=1-6）系列双二苯基膦烷烃化合物。该类化合物是四电子供体，具有较强的电子给与能力，是较好的桥连和螯合配体，和许多金属离子能形成较稳定的配合物。结果表明，反应在高纯氮气保护下，采用超声波照射，反应温度控制在10℃以下，产品收率提高了30％，经元素分析、红外光谱和熔点测定等手段，证明产品的化学结构同理论吻合。Di （diphenylphosphine） -alkanes, Ph2 P （ CH2 ） ,PPh= （ n = 1 =6 ） were synthesized by using lithium, triphenylphosphine and alkane dichloride as raw materials. The complexes is electron donor, which has strong energy of electron donor. The matter is better chelated extractant-bridgedand which can product very steady coordination complex with a lot of metal ions. The results showed that the yield of product increased by 30% when the reaction was irradiated by ultrasonic wave in pure nitrogen with the tempera- ture under 10℃, the structure of product was right with determining by element analysis, IR, melting point.

关 键 词：三苯基膦 合成 溶剂 温度 

分 类 号：O614.121[理学—无机化学]