油酸封端的C_(36)二聚酸/PEG/PPG聚酯的合成及其消泡抑泡性能  被引量:7

Synthesis and defoaming performance of polyester by condensation of C_(36) dimer fatty acid and PEG/PPG with oleic acid as end block

在线阅读下载全文

作  者:冯光炷[1] 崔英德[2] 卢奎[1] 李和平[3] 

机构地区:[1]西北工业大学材料学院,陕西西安710072 [2]仲恺农业技术学院,广东广州510225 [3]河南工业大学化学化工学院,河南郑州450052

出  处:《日用化学工业》2006年第2期76-80,共5页China Surfactant Detergent & Cosmetics

基  金:河南省自然科学基金资助项目(0511021000)

摘  要:采用C36二聚脂肪酸为原料,与聚乙二醇(PEG)和聚丙二醇(PPG)缩聚后,用油酸封端,合成了聚酯型高分子表面活性剂,研究了反应物摩尔比、反应温度、反应时间、催化剂及带水剂用量对产物的消泡和抑泡性能的影响。结果表明,较佳反应条件为:n(C36二聚酸)∶n(油酸)∶n(PEG)∶n(PPG)=0.035∶0.020∶0.030∶0.020,180℃下反应2.5 h,二聚酸用量为19.6 g时,催化剂对甲苯磺酸用量为0.3 g,带水剂甲苯用量为15 mL。与商品有机硅及复配型的聚醚类消泡剂比较后发现,所合成的聚酯水基消泡剂具有更好的消泡和抑泡性能。Polyester type macro- molecular surfactant was synthesized by condensation of C36 fatty acid and PEG/PPG with oleic acid as the end blocking agent. The effects of molar ratio of the reactants, the reaction temperature and reaction time, as well as the dosage of catalyst and water carrying agent with respect to the defoaming performance of the product were investi- gated. The experimental results showed that, the optimal molar ratio is n(C36 dimer fatty acid) : n(oleic acid): n(PEG) : n(PPG) = 0,035:0.020:0.030:0.020; the reaction temperature is 180 ℃ for 2.5 h. When the amount of reactant dimer fatty acid is 19.6 g, the dosage of catalyst (p - toluene sulfonic acid) is 0.3 g and the dosage of water carrying agent (toluene) is 15 mL. The product exhibits better defoaming performance as compared with market commodity organo- silicone deforming agent and blended polyether defoaming agent.

关 键 词:聚酯型高分子表面活性剂 C36二聚脂肪酸 合成 消泡 抑泡 

分 类 号:TS743[轻工技术与工程—制浆造纸工程]

 

参考文献:

正在载入数据...

 

二级参考文献:

正在载入数据...

 

耦合文献:

正在载入数据...

 

引证文献:

正在载入数据...

 

二级引证文献:

正在载入数据...

 

同被引文献:

正在载入数据...

 

相关期刊文献:

正在载入数据...

相关的主题
相关的作者对象
相关的机构对象