Hydrothermal Synthesis and Structure of [Mn(C_8H_5NO_4)·H_2O]_n·2nH_2O  

Hydrothermal Synthesis and Structure of [Mn(C_8H_5NO_4)·H_2O]_n·2nH_2O

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作  者:廖秋霞 姚元根 

机构地区:[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

出  处:《Chinese Journal of Structural Chemistry》2006年第4期465-468,共4页结构化学(英文)

基  金:This work was supported by the National Natural Science Foundation of China (No. 20173063), the State Key Basic Research and Development Plan of China (001CB108906) and the NSF of Fujian Province (E0020001)

摘  要:A novel 5-aminoisophthalate compound, [Mn(C8H5NO4)·H2O]n·2nH2O 1, has been synthesized by the hydrothermal assembly of 5-aminoisophthalic acid with manganese acetate. Elemental analysis, X-ray crystal structure analyses, IR spectra, Fr-Raman and ESR were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in triclinic, space group P1^- with a = 7.7562(2), b = 8.6121(3), c = 8.7107(2)A^°, α = 85.411(2), β = 76.030(2), γ = 66.510(2)°, V = 517.76(3)A^°3, MnC8H11NO7, Mr = 288.12, Z = 2, Dc = 1. 848 g/cm^3, μ= 1.300 mm^-1, F(000) = 294, R = 0.0381 and wR = 0.1043 for 1652 observed reflections (1 〉 20(/)).A novel 5-aminoisophthalate compound, [Mn(C8H5NO4)·H2O]n·2nH2O 1, has been synthesized by the hydrothermal assembly of 5-aminoisophthalic acid with manganese acetate. Elemental analysis, X-ray crystal structure analyses, IR spectra, Fr-Raman and ESR were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in triclinic, space group P1^- with a = 7.7562(2), b = 8.6121(3), c = 8.7107(2)A^°, α = 85.411(2), β = 76.030(2), γ = 66.510(2)°, V = 517.76(3)A^°3, MnC8H11NO7, Mr = 288.12, Z = 2, Dc = 1. 848 g/cm^3, μ= 1.300 mm^-1, F(000) = 294, R = 0.0381 and wR = 0.1043 for 1652 observed reflections (1 〉 20(/)).

关 键 词:crystal structure 5-aminoisophthalic acid manganese complex 

分 类 号:O627.7[理学—有机化学]

 

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