Synthesis and Crystal Structure of a New Ternary Mixed Ligand Complex [Cu(ampym)(bapa)Cl](ClO_4) (ampym = 2-Aminopyrimidine, bapa = Bi(3-aminopropyl)amine)  

作　　者：许同桃 高健 许兴友 杨绪杰 陆路德 汪信 

机构地区：[1]Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094, China Department of Chemical Engineering, Lianyungang Technical College, Lianyungang 222006, China [2]Department of Chemical Engineering, Lianyungang Technical College, Lianyungang 222006, China [3]Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094, China Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China [4]Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094, China

出　　处：《Chinese Journal of Structural Chemistry》2006年第4期469-472,共4页结构化学（英文）

基　　金：This project was supported by the Foundation of Science Committee of Jiangsu province (BK2005045)

摘　　要：The title complex [Cu（ampym）（bapa）Cl]（ClO4） （C10H22Cl2CuN6O4） was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The crystal crystallizes in the orthorhombic system, space group Pna21 with a = 11.9904（12）, b = 15.9796（16）, c = 8.9 i 43（9） A^°, V = 1708.0（3）A^°3 Mr = 424.78, Z = 4, F（000） = 876, Dc = 1.652 g/cm^3, T = 293 K,μ =1 .619 mm^-1 and λ=0.71073 A^°. The structure was refined to R = 0.0240 and wR ： 0.0564 for 2905 observed reflections with I 〉 2σ（I）. Flack = 0.039（12）.The title complex [Cu（ampym）（bapa）Cl]（ClO4） （C10H22Cl2CuN6O4） was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The crystal crystallizes in the orthorhombic system, space group Pna21 with a = 11.9904（12）, b = 15.9796（16）, c = 8.9 i 43（9） A^°, V = 1708.0（3）A^°3 Mr = 424.78, Z = 4, F（000） = 876, Dc = 1.652 g/cm^3, T = 293 K,μ =1 .619 mm^-1 and λ=0.71073 A^°. The structure was refined to R = 0.0240 and wR ： 0.0564 for 2905 observed reflections with I 〉 2σ（I）. Flack = 0.039（12）.

关 键 词：2-AMINOPYRIMIDINE bi（3-aminopropyl）amine copper complex crystal structure 

分 类 号：O621.25[理学—有机化学]