硒钼钒杂多配合物的合成与表征  

Synthesis and Characterization of Two Unrecedented Heteropolymetalatates[Se_2Mo_2V_4O_(24)]^(8-) and [Se_2Mo_3V_3O_(24)]^(7-)

作　　者：张平宇[1] 王薇[2] 吴集贵[2] 

机构地区：[1]兰州大学西部环境教育部重点实验室,甘肃兰州730000 [2]兰州大学化学化工学院,甘肃兰州730000

出　　处：《化学研究与应用》2006年第4期403-405,共3页Chemical Research and Application

基　　金：国家自然科学基金资助(40301050)

摘　　要：Two New heteropoly molydovanadateselenite complexes with formulas[Se2Mo2V4O24]8-and[Se2Mo3V3O24]7- were reported for the first time.These complexes were isolated at pH=2.It is proved that the ratios of Mo and V in materidal influence the constitution of complexes.These complexes were characterized by elemental analysis,IR,UV,XRD,molar conductance and TG-DTA.It is deduced that these complexes may have the basic skeleton of X2M6 structure.Two New heteropoly molydovanadateselenite complexes with formulas[ Se2Mo2V4O24]^8- and [ Se2Mo3V3O24]^7- were reported for the first time. These complexes were isolated at pH = 2. It is proved that the ratios of Mo and V in materidal influence the constitution of complexes. These complexes were characterized by elemental analysis, IR, UV, XRD, molar conductance and TGDTA. It is deduced that these complexes may have the basic skeleton of X2M6 structure.

关 键 词：硒钼钒三元杂多配合物 合成与表征 X2M6的结构 

分 类 号：O611.4[理学—无机化学]